Solvent-induced lone pair activity tuning and vapoluminescence in a Pt 2Pb cluster

  1. Berenguer, J.R. 1
  2. Lalinde, E. 1
  3. Martín, A. 2
  4. Moreno, M.T. 1
  5. Ruiz, S. 1
  6. Sánchez, S. 1
  7. Shahsavari, H.R. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Chemical Communications

ISSN: 1359-7345

Año de publicación: 2013

Volumen: 49

Número: 44

Páginas: 5067-5069

Tipo: Artículo

DOI: 10.1039/C3CC41638K SCOPUS: 2-s2.0-84877661037 WoS: WOS:000318561500027 GOOGLE SCHOLAR

Otras publicaciones en: Chemical Communications

Resumen

We report a novel cluster, [{Pt(C6F5)(bzq)} 2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the PbII in the ground state and to the distinct distortion of the coordination environment (1 and 1-solvent) upon photoexcitation. This journal is © The Royal Society of Chemistry 2013.