Comparative study of (N, Fe) doped TiO2 photocatalysts

  1. Larumbe, S. 1
  2. Monge, M. 2
  3. Gómez-Polo, C. 1
  1. 1 Universidad Pública de Navarra
    info

    Universidad Pública de Navarra

    Pamplona, España

    ROR https://ror.org/02z0cah89

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Applied Surface Science

ISSN: 0169-4332

Año de publicación: 2015

Volumen: 327

Páginas: 490-497

Tipo: Artículo

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DOI: 10.1016/J.APSUSC.2014.11.137 SCOPUS: 2-s2.0-84921690382 WoS: WOS:000348453800067 GOOGLE SCHOLAR

Otras publicaciones en: Applied Surface Science

Objetivos de desarrollo sostenible

Resumen

The effect of N and Fe doping on the structural, optical, photocatalytic and magnetic properties of TiO2 nanoparticles is analyzed. Undoped, N and Fe doped TiO2 nanoparticles were synthesized by sol-gel method. Titanium tetraisopropoxide (TTIP) was used as the alkoxyde precursor and iron (III) nitrate and urea were the employed precursors to obtain Fe and N doped TiO2 nanoparticles, respectively. Differential Scanning Calorimetry (DSC) and Thermogravimetrical Analysis (TGA) enabled the analysis of the thermal decomposition process and the final calcination temperature. X-Ray Diffraction patterns of the calcined nanoparticles displayed a monophasic anatase structure in all the samples with mean crystallite diameter around 4-6 nm. The introduction of Fe or N induced a red-shift in the absorption spectra. Such a red-shift is characterized by a decrease in the band-gap energy and the occurrence of an absorption (Urbach) tail in the visible region. Finally, the photocatalytic efficiency was evaluated under UV and Visible light, obtaining an improvement of the kinetic constants in the nitrogen doped TiO2 nanoparticles with respect to undoped and Fe doped TiO2. The differences in the photocatalytic response under Fe and N doping are also analyzed in terms of the magnetic response of the analyzed photocatalysts.