Influence of crown thioether ligands in the structures and of perhalophenyl groups in the optical properties of complexes with argentoaurophilic interactions

  1. Blake, A.J. 3
  2. Donamaria, R. 1
  3. Lippolis, V. 2
  4. López-De-Luzuriaga, J.M. 1
  5. Manso, E. 1
  6. Monge, M. 1
  7. Olmos, M.E. 1
  1. 1 Universidad de La Rioja

    Universidad de La Rioja

    Logroño, España

    GRID grid.119021.a

  2. 2 University of Cagliari

    University of Cagliari

    Cagliari, Italia

    GRID grid.7763.5

  3. 3 University of Nottingham

    University of Nottingham

    Nottingham, Reino Unido

    GRID grid.4563.4

Inorganic Chemistry

ISSN: 0020-1669

Ano de publicación: 2014

Volume: 53

Número: 19

Páxinas: 10471-10484

Tipo: Artigo

Exportar: RIS
DOI: 10.1021/ic501515c SCOPUS: 2-s2.0-84907833619 WoS: 000342856800060 GOOGLE SCHOLAR


Citas recibidas

  • Citas en Scopus: 13 (07-10-2021)

JCR (Journal Impact Factor)

  • Ano 2014
  • Factor de impacto da revista: 4.762
  • Cuartil maior: Q1
  • Área: CHEMISTRY, INORGANIC & NUCLEAR Cuartil: Q1 Posición na área: 4/45 (Edición: SCIE)

SCImago Journal Rank

  • Ano 2014
  • Impacto SJR da revista: 1.867
  • Cuartil maior: Q1
  • Área: Chemistry (miscellaneous) Cuartil: Q1 Posición na área: 31/453
  • Área: Inorganic Chemistry Cuartil: Q1 Posición na área: 7/74
  • Área: Physical and Theoretical Chemistry Cuartil: Q1 Posición na área: 19/168


  • Ano 2014
  • CiteScore da revista: 8.2
  • Área: Inorganic Chemistry Percentil: 96
  • Área: Physical and Theoretical Chemistry Percentil: 89
  • Área: Medicine (all) Percentil: 89


Reaction of [{Au(C6X5)2}Ag]n (X = Cl, F) with the crown thioethers 1,4,7-trithiacyclononane ([9]aneS3), 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4), or 1,4,7,10,13,16,19,22-octathiacyclotetracosane ([24]aneS8) affords a series of heteronuclear AuI/AgI compounds of stoichiometry [{Au(C6X5)2}Ag(L)x] (L = [9]aneS3, x = 2 (1, 4); L = [14]aneS4, x = 1 (2, 5); L = [24]aneS8, x = 0.5 (3, 6)) formed via Ag-S bonds and Au···Ag contacts. X-ray diffraction studies of some of these complexes reveal different structural arrangements and nuclearity depending on the nature of the crown thioether ligand and on the presence or absence of aurophilic interactions. All the complexes are luminescent in the solid state but not in solution. Density functional theory calculations on representative model systems of complexes 2-4 and 6 were carried out to determine the origin of the electronic transitions responsible for their optical properties, which strongly depend on the nature of the perhalophenyl groups bonded to gold.