Coordination of a Monomeric Diphosphido Platinum Complex as a Bridging Ligand.

  1. Berenguer, J.R. 1
  2. Chaouche, N. 2
  3. Forniés, J. 2
  4. Fortuño, C. 2
  5. Martín, A. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Journal:
New Journal of Chemistry

ISSN: 1144-0546

Year of publication: 2006

Volume: 30

Issue: 3

Pages: 473-478

Type: Article

beta Ver similares en nube de resultados
DOI: 10.1039/B517726J SCOPUS: 2-s2.0-33644921795 WoS: WOS:000235992600024 DIALNET GOOGLE SCHOLAR

More publications in: New Journal of Chemistry

Institutional repository: lock_openOpen access Editor

Sustainable development goals

Abstract

The reactions of cis-[Pt(C6F5)2(PPh 2)2]2- with [AuClPPh3] or [Ag(OClO3)PPh3] yield the neutral heterotrinuclear complexes [M2Pt(μ-PPh2)2(C6F 5)2(PPh3)2] (M = Au, Ag). Their structures have been established by X-ray diffraction studies and both complexes display M⋯M interactions but not Pt-M bonds. They are dynamic in solution, as demonstrated by 19F NMR spectroscopy, and M⋯M interactions seem to be present at low temperature. © the Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2006.