Analysis of product Doppler-broadened profiles generated from photoinitiated bimolecular reactions

  1. Aoiz, F.J. 23
  2. Brouard, M. 3
  3. Enriquez, P.A. 3
  4. Sayos, R. 13
  1. 1 Universitat de Barcelona
    info

    Universitat de Barcelona

    Barcelona, España

    ROR https://ror.org/021018s57

  2. 2 Universidad Complutense de Madrid
    info

    Universidad Complutense de Madrid

    Madrid, España

    ROR 02p0gd045

  3. 3 University of Nottingham
    info

    University of Nottingham

    Nottingham, Reino Unido

    ROR https://ror.org/01ee9ar58

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Journal:
Journal of the Chemical Society. Faraday transactions Print

ISSN: 0956-5000

Year of publication: 1993

Volume: 89

Issue: 10

Pages: 1427-1434

Type: Article

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DOI: 10.1039/FT9938901427 SCOPUS: 2-s2.0-8344246368 GOOGLE SCHOLAR

More publications in: Journal of the Chemical Society. Faraday transactions Print

Abstract

This paper, which is the companion to the experimental paper (M. Brouard, S. P. Duxon, P. A. Enriquez and J. P. Simons, J. Chem. Soc., Faraday Trans., 1993, 89, 1435) in this issue, is divided into two parts. In the first, equations for the laboratory (LAB) velocity distribution of products generated via photoionitiated bimolecular reaction are presented. These equations provide the basis for numerical simulation of these distributions from assumed forms for the centre-of-mass (CM) differential cross-section: the results may be compared directly with those derived experimentally via Fourier-transform Doppler 1 + 1 LIF or REMPI spectroscopy. The latter inversion technique is described in detail in the second part of the paper.