Fluorescence decay lifetimes of the B and A states of Te2

  1. Martinez, E. 1
  2. Basterrechea, F.J. 1
  3. Puyuelo, P. 1
  4. Castano, F. 1
  1. 1 Universidad del País Vasco/Euskal Herriko Unibertsitatea
    info

    Universidad del País Vasco/Euskal Herriko Unibertsitatea

    Lejona, España

    ROR https://ror.org/000xsnr85

Revista:
Journal of Physical Chemistry B

ISSN: 1520-6106

Año de publicación: 1990

Volumen: 23

Número: 1

Páginas: 77-84

Tipo: Artículo

SCOPUS: 2-s2.0-14344282658 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Physical Chemistry B

Resumen

Fluorescence lifetimes from different vibrational levels of the B(0 u +) and A(0u +) excited states of Te2 were measured following laser excitation between 468 and 492 nm. A radiative lifetime of 80+or-6 ns was determined for low vibrational levels (v=0-6) of the B(0u +) state. Lifetimes for vibrational levels of the A state were measured, resulting in smaller values than those previously reported for low vibrational levels. Results suggest a perturbation mechanism in the A state that becomes stronger as v increases. Dipole transition moments for the A-X and B-X transitions were calculated from the measured radiative lifetimes.