Synthesis and Characterization of Thiolato-Bridged Titanium-Platinum and Palladium Heterobinuclear Complexes. Molecular Structure of [(eta5-C5H4SiMe3)2Ti(mu-SPh)2Pd(C6F5)2]

  1. Amador, U. 4
  2. Delgado, E. 2
  3. Forniés, J. 2
  4. Hernández, E. 2
  5. Lalinde, E. 1
  6. Moreno, M.T. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Universidad Autónoma de Madrid
    info

    Universidad Autónoma de Madrid

    Madrid, España

    ROR https://ror.org/01cby8j38

  4. 4 Universidad Complutense de Madrid
    info

    Universidad Complutense de Madrid

    Madrid, España

    ROR 02p0gd045

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Revue:
Inorganic Chemistry

ISSN: 0020-1669

Année de publication: 1995

Volumen: 34

Número: 21

Pages: 5279-5284

Type: Article

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SCOPUS: 2-s2.0-0001217134 WoS: WOS:A1995RZ39800029 GOOGLE SCHOLAR

D'autres publications dans: Inorganic Chemistry

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Résumé

A series of titanium-platinum and -palladium heterobinuclear compounds with double thiolato bridges, [(η5-C5H4R′) 2Ti(μ-SR)2M(C6F5)2] (R′ = H, SiMe3; R = Ph, C6F5; M = Pd, Pt), has been prepared. The crystal structure of [(η5-C5H4SiMe3) 2Ti(μ-SPh)2Pd(C6F5)2] has been established by single-crystal X-ray crystallography: the complex crystallizes in the monoclinic system in space group P21lc; a= 10.237 (2) Å; b = 14.635 (3) Å; c = 27.651 (6) Å; β = 90.83 (2)°; Z = 4; and R = 0.056. The titanium atom is in pseudotetrahedral coordination environment, whereas the palladium is square-planar. The phenyl groups on the sulfur atoms adopt an endo (syn) arrangement with respect to the central Ti-S2-Pd core. © 1995 American Chemical Society.