Neutral PtAg2 Clusters containing Unsymmetrical mu3-sigma and mu-eta2,sigma- Alkynyl Groups. Crystal Structure of [PtAg2(C6F5)2(mu-eta2,sigma-C=CPh)(mu3-sigma-C=CPh)(PPh3)2]. 0,25CH2Cl2
- Ara, I. 2
- Forniés, J. 2
- Lalinde, E. 1
- Moreno, M.T. 1
- Tomás, M. 2
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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ISSN: 0300-9246
Año de publicación: 1994
Volumen: 18
Páginas: 2735-2736
Tipo: Artículo
beta Ver similares en nube de resultadosOtras publicaciones en: Journal of the Chemical Society-Dalton Transactions
Resumen
The reaction between [{PtAg2(C6F5)2(C≡CR) 2}n] and triphenylphosphine in a molar ratio of 1: 2 has resulted in a good yield of the trinuclear mixed-metal complexes [PtAg2(C6F5)2(μ-η 2,σ-C≡CR)(μ3-σ-C≡CR)(PPh 3)2] (R = Ph 3 or But 4), and the crystal structure of 3 revealed that they contain two different types of unsymmetrical μ3-σ and μ-η2, σ-edge-bridging alkynyl ligands.