Unusual stabilization of cationic "M(eta3-allyl)+" (M = Pt, Pd) units by a dianionic cis-Pt(C6F5)2(C=CSiMe3)2- fragment
- Berenguer, J.R. 2
- Forniés, J. 2
- Lalinde, E. 1
- Martínez, F. 2
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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ISSN: 0022-328X
Year of publication: 1994
Volume: 470
Issue: 1-2
Pages: 15-18
Type: Article
beta Ver similares en nube de resultadosMore publications in: Journal of Organometallic Chemistry
Abstract
Chloride abstraction from [{M(η3 C3H5)Cl}n] (M Pt, n = 4 or M Pd, n = 2) by (NBu4)2[cis-Pt(C6F5)2(CCSiMe3)2] (1) gives rise to novel homo- and hetero-dinuclear zwitterionic derivatives (NBu4) [{cis-Pt(C6F5)2(CCSiMe3)2}M(η3-C3H5)] (M Pt 2; M Pd 3) which are formed by a M(η3-allyl)+ unit attached to both alkynyl ligands of the {cis-Pt(C6F5)2(CCSiMe3)2}2- fragment. The structure of 3 has been established by X-ray diffraction. © 1994.