Unusual bridging of the metal centers in a heterometallic titanium-platinum complex. X-ray structure of [Cp2Ti(mu2-eta1-C=CtBu)2Pt(C6F5)2]·CH2Cl2

  1. Berenguer, J.R. 2
  2. Falvello, L.R. 2
  3. Forniés, J. 2
  4. Lalinde, E. 1
  5. Tomás, M. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Revista:
Organometallics

ISSN: 0276-7333

Ano de publicación: 1993

Volume: 12

Número: 1

Páxinas: 6-7

Tipo: Artigo

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SCOPUS: 2-s2.0-0002880303 WoS: WOS:A1993KH30300003 GOOGLE SCHOLAR

Outras publicacións en: Organometallics

Repositorio institucional: lock_openAcceso aberto Editor

Resumo

The reaction between [Cp2Ti(C≡CtBu)2] (1) and [cis-Pt(C6F5)2(THF)2] gives the mixed complex [Cp2-Ti(μ2-η1-C≡C tBu)2Pt(C6F5)2] (2), which has been shown by X-ray crystallography to contain a system of two asymmetric μ2-η1-alkynyl ligands bridging both metal centers. Complex 2 crystallizes as the dichloromethane solvate in the monoclinic crystal system, space group P21/n, with a = 133.725 (2) Å, b = 15.875 (2) Å, c = 16.424 (3) Å, β = 99.58 (2)°, V = 3529 (1) Å3, and Z = 4. A model of 447 parameters was refined to 3586 diffraction data, giving residuals of R = 0.0390, Rw = 0.0558, and quality-of-fit = 1.367. The Pt-Ti distance is 2.831 (2) Å. © 1993 American Chemical Society.