Terminal pentafluorobenzimidoyl palladium(II) complexes. X-ray structure of trans-[Pd{C(C6 F5)=NMe}Cl(CNMe)2 ]

  1. Usón, R. 1
  2. Forniés, J. 1
  3. Espinet, P. 1
  4. Lalinde, E. 1
  5. Jones, P.G. 2
  6. Sheldrick, G.M. 2
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 University of Göttingen
    info

    University of Göttingen

    Gotinga, Alemania

    ROR https://ror.org/01y9bpm73

Revue:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Année de publication: 1985

Volumen: 288

Número: 2

Pages: 249-259

Type: Article

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D'autres publications dans: Journal of Organometallic Chemistry

Résumé

The preparations of the complexes trans-[Pd{C(C6F5)N(R1)}Cl(CNR2)2] and [Pd{C(C6F5)N(R1)}(CNR2)2]X (R1 = Me, p-Tol; R2 = Me, p-Tol, But; X = ClO4 or BPh4) from [Pd2{μ-C(C6F5)N(R1)}2Cl2(CNR2)2] are described. The splitting of the imidoyl bridges is accompanied by an isomerization of the imidoyl group from the syn to the anti conformation as shown by a single crystal X-ray diffraction study of trans-[Pd{C(C6F5)N(Me)}Cl(CNMe)2]. Attempted preparations of [Pd{C(C6F5)=N(R1)}Cl(PPh3)2] from [Pd2-C(C6F5)N(R1)}2Cl2(PPh3)2] led to elimination of CNR and formation of trans-[Pd(C6F5)Cl(PPh3)2]; this is the first example of isonitrile elimination in palladium chemistry. © 1985.