Fiber Optic-Based Interface for On-Line Selective Photometric Determinations of Solid Samples by Supercritical Fluid Extraction

  1. Tena, M.T. 1
  2. Valcárcel, M. 1
  1. 1 Universidad de Córdoba
    info

    Universidad de Córdoba

    Córdoba, España

    ROR https://ror.org/05yc77b46

Revista:
Journal of Chromatography A

ISSN: 0021-9673

Año de publicación: 1996

Volumen: 753

Número: 2

Páginas: 299-305

Tipo: Artículo

DOI: 10.1016/S0021-9673(96)00563-8 SCOPUS: 2-s2.0-0029969017 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Chromatography A

Repositorio institucional: lock_openAcceso abierto Editor

Resumen

A novel windowless fiber optic-based flow-cell constructed from a drilled stainless steel block was used to link a supercritical fluid extractor and a spectrophotometer in order to obtain qualitative and quantitative information from the supercritical extract during the supercritical fluid extraction (SFE) process. The coupled system allows the process to be optimized in terms of extraction rate and extraction yield from the shape of the extraction curve and the area under it, respectively. The SFE of ground coffee samples was monitored spectrophotometrically and the suppression of the contribution of coextracted compounds to the analytical signal was demonstrated from derivative spectra.