Gold-Heterometal complexes. Evolution of a new class of luminescent materials

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. López-De-Luzuriaga, J.M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Revista:
Dalton Transactions

ISSN: 1477-9226

Any de publicació: 2007

Volum: 20

Pàgines: 1969-1981

Tipus: Article

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DOI: 10.1039/B702838P SCOPUS: 2-s2.0-34248654559 WoS: WOS:000246486600001 GOOGLE SCHOLAR

Altres publicacions en: Dalton Transactions

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Resum

A very promising area of research in which metallophilic attraction has become the dominating factor determining the structural patterns that give rise to luminescent materials is discussed. In addition to the intrinsic conditions that a gold complex requires to show luminescence, we show how the type and number of the ligands, the coordination environments around the metal centres, the temperature, the heterometal, the metal-metal distances, etc., increase the possibilities of electronic transitions and, hence, multiply the factors that affect the energy and number of emissions. We think that far from being a hindrance or a problem these findings actually give rise to a fascinating area of research with promising future applications, for instance, in imaging technology, vapour sensors, light emitting devices or even medicine, where the demand for optoelectronic devices is increasing every day. This journal is © The Royal Society of Chemistry.