Zn-mediated catalytic photoreduction of aldimines. One-pot synthesis and separation of meso and d,l C2 symmetrical diamines

  1. Ortega, M. 1
  2. Rodríguez, M.A. 1
  3. Campos, P.J. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Aldizkaria:
Tetrahedron

ISSN: 0040-4020

Argitalpen urtea: 2004

Alea: 60

Zenbakia: 31

Orrialdeak: 6475-6478

Mota: Artikulua

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DOI: 10.1016/J.TET.2004.06.029 SCOPUS: 2-s2.0-4143067286 WoS: WOS:000222863600006 GOOGLE SCHOLAR

Beste argitalpen batzuk: Tetrahedron

Gordailu instituzionala: lock_openSarbide irekia Editor

Garapen Iraunkorreko Helburuak

Laburpena

A new one-pot method for the synthesis and selective separation of 1,2-diamines is reported. The methodology, which involves the photoreduction of imines using catalytic amounts of zinc as a photosensitizer, allows the direct preparation and separation of meso and d,l compounds on a multigram scale. © 2004 Elsevier Ltd. All rights reserved.