Simple and versatile synthesis of 1-pyrroline derivatives through thermal rearrangement of N-cyclopropilimines

  1. Campos, P.J. 1
  2. Soldevilla, A. 1
  3. Sampedro, D. 1
  4. Rodríguez, M.A. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Tetrahedron Letters

ISSN: 0040-4039

Ano de publicación: 2002

Volume: 43

Número: 49

Páxinas: 8811-8813

Tipo: Artigo

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DOI: 10.1016/S0040-4039(02)02238-4 SCOPUS: 2-s2.0-0037010776 WoS: WOS:000179238400001 GOOGLE SCHOLAR

Outras publicacións en: Tetrahedron Letters

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Resumo

N-Cyclopropylimines rearrange under thermal conditions to give 1-pyrrolines. The effect of imine and cyclopropane substitution is explored. This methodology allows the presence of different substituents (alkyl, alkenyl, aryl) and the reaction proceeds regiospecifically. © 2002 Elsevier Science Ltd. All rights reserved.