Photoreductive Coupling of Aldimines. Synthesis of C2 Symmetrical Diamines

  1. Campos, P.J. 1
  2. Arranz, J. 1
  3. Rodríguez, M.A. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Zeitschrift:
Tetrahedron

ISSN: 0040-4020

Datum der Publikation: 2000

Ausgabe: 56

Nummer: 37

Seiten: 7285-7289

Art: Artikel

Andere Publikationen in: Tetrahedron

Institutionelles Repository: lock_openOpen Access Editor

Zusammenfassung

The photoreductive coupling of pyridine-, arene- and alkynecarboxaldimines is a very convenient procedure for the preparation of vicinal diamines in good to excellent yields. The usual trend gave an excess of meso diamine, which enhances the usefulness of this method. The procedure tolerates bulky groups such as tert-butyl and diphenylmethyl on the nitrogen atom. (C) 2000 Elsevier Science Ltd.