Photochemistry of Imine-Group VI Carbene Complexes: A Novel Reactivity Involving a Cyclopentannulation Reaction

  1. Campos, P.J. 1
  2. Sampedro, D. 1
  3. Rodríguez, M.A. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Aldizkaria:
Organometallics

ISSN: 0276-7333

Argitalpen urtea: 2000

Alea: 19

Zenbakia: 16

Orrialdeak: 3082-3084

Mota: Artikulua

DOI: 10.1021/OM000248X SCOPUS: 2-s2.0-0034248664 WoS: WOS:000088605400019 GOOGLE SCHOLAR

Beste argitalpen batzuk: Organometallics

Gordailu instituzionala: lock_openSarbide irekia Editor

Laburpena

3-Aza-1-chroma-1,3-butadiene undergoes photochemical [3 + 2] cyclopentannulation with alkenes and alkynes instead of the expected benzannulation or cyclobutannulation reactions, providing a good method for the synthesis of 1-pyrroline and 2H-pyrrole derivatives. This photochemical reaction can be extended to molybdenum and tungsten carbene complexes.