Organometallic phosphors as building blocks in sol-gel chemistry: Luminescent organometallo-silica materials

  1. Ezquerro, C. 1
  2. Sepúlveda, A.E. 1
  3. Grau-Atienza, A. 2
  4. Serrano, E. 2
  5. Lalinde, E. 1
  6. Berenguer, J.R. 1
  7. García-Martínez, J. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Universitat d'Alacant
    info

    Universitat d'Alacant

    Alicante, España

    ROR https://ror.org/05t8bcz72

Journal:
Journal of Materials Chemistry C . Materials for optical, magnetic and electronic devices

ISSN: 2050-7526

Year of publication: 2017

Volume: 5

Issue: 37

Pages: 9721-9732

Type: Article

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DOI: 10.1039/C7TC02188G SCOPUS: 2-s2.0-85030255510 WoS: WOS:000412069100025 GOOGLE SCHOLAR

More publications in: Journal of Materials Chemistry C . Materials for optical, magnetic and electronic devices

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Abstract

In this study, a series of luminescent mesoporous hybrid organometallo-silica materials were successfully prepared via sol-gel coordination chemistry. The condensation of organometallic Ir(iii) and Pt(ii) complexes containing a 2-(diphenylphosphino)ethyltriethoxysilane (PPETS) ligand with the silica precursor (TEOS) yielded hybrid materials with homogeneous metal incorporation in the silica network and excellent luminescent and textural properties. All the reactions were carried out at room temperature and in the absence of a surfactant. Powders and transparent gels were prepared by adjusting the synthesis conditions and amounts of incorporated organometallic complex, yielding very stable emissive materials. © 2017 The Royal Society of Chemistry.