Lead encapsulation by a golden clamp through multiple electrostatic, metallophilic, hydrogen bonding and weak interactions

  1. Echeverría, R. 1
  2. López-De-Luzuriaga, J.M. 1
  3. Monge, M. 1
  4. Moreno, S. 1
  5. Olmos, M.E. 1
  6. Rodríguez-Castillo, M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    GRID grid.119021.a

Journal:
Chemical Communications

ISSN: 1359-7345

Year of publication: 2018

Volume: 54

Issue: 3

Pages: 295-298

Type: Article

Export: RIS
DOI: 10.1039/c7cc08710a SCOPUS: 2-s2.0-85040191387 WoS: 000419142200016 GOOGLE SCHOLAR

Metrics

Cited by

  • Scopus Cited by: 8 (12-11-2021)

JCR (Journal Impact Factor)

  • Year 2018
  • Journal Impact Factor: 6.164
  • Best Quartile: Q1
  • Area: CHEMISTRY, MULTIDISCIPLINARY Quartile: Q1 Rank in area: 32/172 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2018
  • SJR Journal Impact: 2.177
  • Best Quartile: Q1
  • Area: Catalysis Quartile: Q1 Rank in area: 7/60
  • Area: Ceramics and Composites Quartile: Q1 Rank in area: 5/133
  • Area: Chemistry (miscellaneous) Quartile: Q1 Rank in area: 27/468
  • Area: Electronic, Optical and Magnetic Materials Quartile: Q1 Rank in area: 19/444
  • Area: Materials Chemistry Quartile: Q1 Rank in area: 12/318
  • Area: Metals and Alloys Quartile: Q1 Rank in area: 7/190
  • Area: Surfaces, Coatings and Films Quartile: Q1 Rank in area: 5/156

CiteScore

  • Year 2018
  • CiteScore of the Journal : 11.6
  • Area: Metals and Alloys Percentile: 97
  • Area: Ceramics and Composites Percentile: 96
  • Area: Surfaces, Coatings and Films Percentile: 96
  • Area: Materials Chemistry Percentile: 96
  • Area: Electronic, Optical and Magnetic Materials Percentile: 93
  • Area: Chemistry (all) Percentile: 92
  • Area: Catalysis Percentile: 88

Journal Citation Indicator (JCI)

  • Year 2018
  • Journal Citation Indicator (JCI): 1.31
  • Best Quartile: Q1
  • Area: CHEMISTRY, MULTIDISCIPLINARY Quartile: Q1 Rank in area: 33/212

Abstract

The structure of the complex [{Pb(HBpz3)}{Au3(o-C6BrF4)3(HBpz3)}] consists of a host-guest heterometallic system built up through a plethora of interactions including electrostatic, metallophilic, H-bonding, Au⋯Br or weak C⋯C or Pb⋯Br contacts. Computational studies show that the dispersive interactions are responsible for the attraction of the Pb(ii) cationic moiety within the basket-like trinuclear Au(i) fragment, whereas the ionic component of the interaction placed at the rings produces a molecular clamp. © 2018 The Royal Society of Chemistry.