An Efficient Method for the Copper(II)-promoted Stereoselective Iodofunctionalization of Alkenes

  1. Barluenga, J. 1
  2. Rodríguez, M.A. 1
  3. Campos, P.J. 1
  1. 1 Universidad de Oviedo
    info

    Universidad de Oviedo

    Oviedo, España

    ROR https://ror.org/006gksa02

Revista:
Journal of the Chemical Society. Perkin Transactions 1 2001

ISSN: 1472-7781

Any de publicació: 1990

Volum: 10

Pàgines: 2807-2809

Tipus: Article

SCOPUS: 2-s2.0-37049087629 GOOGLE SCHOLAR

Altres publicacions en: Journal of the Chemical Society. Perkin Transactions 1 2001

Repositori institucional: lock_openAccés obert Editor

Resum

A mixture of iodine and CuO·HBF4 reacts stereoselectively with alkenes in the presence of a wide variety of nucleophiles (water, MeOH, HCO2H, AcOH, EtCO2H, NaNO2, KSCN, NaSO 2Ar, LiCl, LiBr, Nal, Et3SiH, and MeOPh) to give the corresponding 2-functionalized iodo compounds. A regio-chemistry study is also reported.