A New Electrophilic Addition to Acetylenes. Synthesis of 1,2-Iodofunctionalized Olefins

  1. Barluenga, J. 1
  2. Rodríguez, M.A. 1
  3. González, J.M. 1
  4. Campos, P.J. 1
  5. Asensio, G. 2
  1. 1 Universidad de Oviedo
    info

    Universidad de Oviedo

    Oviedo, España

    ROR https://ror.org/006gksa02

  2. 2 Universitat de València
    info

    Universitat de València

    Valencia, España

    ROR https://ror.org/043nxc105

Journal:
Tetrahedron Letters

ISSN: 0040-4039

Year of publication: 1986

Volume: 27

Issue: 28

Pages: 3303-3306

Type: Article

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Abstract

Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate (1) in the presence of a wide variety of nucleophiles (F, Cl, Br, I, SCN, pyridine, OAc, anisole, H) to give 1,2-iodofunctionalized olefins (4). © 1986.