Thermodynamics of the partially miscible systems (diacetone alcohol + n-Hexane) between 288.15K and 318.15K

  1. Gracia, M. 1
  2. Baños, I. 1
  3. Pérez, P. 1
  4. Valero, J. 1
  5. Gutiérrezlosa, C. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Journal of Chemical Thermodynamics

ISSN: 0021-9614

Año de publicación: 1992

Volumen: 24

Número: 12

Páginas: 1237-1242

Tipo: Artículo

SCOPUS: 2-s2.0-44049113186 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Chemical Thermodynamics

Resumen

Excess enthalpies and vapour pressures of {x(CH3)2C(OH)CH2COCH3 + (1 - x)CH3(CH2)4CH3} at the temperatures 288.15 K, 293.15 K, 298.15 K, 308.15 K, and 318.15 K were measured. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs energies was carried out by Barker's method. The mixture shows limited miscibility, and a coexistence curve was drawn near the U.C.S.T. TSE m shows a complicated behaviour over the whole temperature range. © 1992 Academic Press Limited All rights reserved.