Weak intermetallic bonding in unusual trinuclear complexes: Crystal structure of [Rh3(μ3-tz)(μ2-Cl) Cl(η4-tfb)(CO)4]·1/2CH2Cl 2 and[Rh3(μ3-tz)...

  1. Oro, L.A. 1
  2. Pinillos, M.T. 1
  3. Tejel, C. 1
  4. FocesFoces, C. 2
  5. Cano, F.H. 2
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Instituto de Química Física Rocasolano
    info

    Instituto de Química Física Rocasolano

    Madrid, España

    ROR https://ror.org/03xk60j79

Revista:
Journal of the Chemical Society - Series Chemical Communications

ISSN: 0022-4936

Año de publicación: 1984

Volumen: 24

Páginas: 1687-1688

Tipo: Artículo

SCOPUS: 2-s2.0-51149219064 GOOGLE SCHOLAR

Otras publicaciones en: Journal of the Chemical Society - Series Chemical Communications

Repositorio institucional: lock_openAcceso abierto Editor

Resumen

full title:Weak intermetallic bonding in unusual trinuclear complexes: Crystal structure of [Rh3(μ3-tz)(μ2-Cl) Cl(η4-tfb)(CO)4]·1/2CH2Cl 2 and[Rh3(μ3-tz)(μ2-Cl) Cl(η3-C3H5)2(CO)4]· 1/2C2H4Cl2 (Htz = 1,2,4-triazole; tfb = tetrafluorobenzobarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene) [Rh(acac)L2] [Hacac = acetylacetone; L2 = η4-tfb (tetrafluorobenzobarrelene), L = η3-C3H5] react with 1,2,4-triazole (Htz) and [RhCl(CO)2]2 to give trinuclear complexes of formula [Rh 3(μ3-tz)(μ2-Cl)ClL2(CO) 4] whose crystal structures, determined by X-ray methods, show intermetallic Rh-Rh distances of 3.425(4) and 3.393(1) Å, respectively.