N-Substituted imidazole derivatives of rhodium(I) and iridium(I) with and without metal-metal interaction. Crystal structure of cis-(CO)2RhCl(N-methylimidazole)

  1. Bonati, F. 1
  2. Oro, L.A. 1
  3. Pinillos, M.T. 1
  4. Tejel, C. 1
  5. Apreda, M.C. 2
  6. Foces-Foces, C. 2
  7. Cano, F.H. 2
  1. 1 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  2. 2 Instituto de Química Física Rocasolano
    info

    Instituto de Química Física Rocasolano

    Madrid, España

    ROR https://ror.org/03xk60j79

Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Año de publicación: 1989

Volumen: 369

Número: 2

Páginas: 253-265

Tipo: Artículo

SCOPUS: 2-s2.0-0000803683 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Organometallic Chemistry

Resumen

Bridge splitting reactions with N-methylimidazole (Rim, R = Me) or N-benzylimidazole (Rim, R = PhCH2) gave cis-L2MCl(Rim) complexes (M = Rh, Ir, L2 = (CO)2, 1,5-cyclooctadiene; M = Rh, L2 = (p-tosylmethyl isocyanide)2 or (CO)(PPh)3). M ... M interactions in the dicarbonyl complexes are revealed by an X-ray diffraction study of cis-(CO)2RhCl(N-methylimidazole). The molecular units pack in the crystal as infinite chains along the c-axis with intermetallic distances Rh ⋯ Rh of 3.2833(5) Å. © 1989.