Five coordinate rhodium(I) complexes containing the thihalogenotin group

  1. Uson, R. 1
  2. Oro, L.A. 1
  3. Pinillos, M.T. 1
  4. Arruebo, A. 1
  5. Starzewski, K.A.O. 2
  6. Pregosin, P.S. 2
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Swiss Federal Institute of Technology in Zurich
    info

    Swiss Federal Institute of Technology in Zurich

    Zúrich, Suiza

    ROR https://ror.org/05a28rw58

Revue:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Année de publication: 1980

Volumen: 192

Número: 2

Pages: 227-233

Type: Article

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Résumé

The preparation and properties of five coordinate rhodium complexes with mono- or bidentate phosphorus donor ligands of the general formulae [Rh(SnCl3)(diolefin)L2], [Rh(SnClX2)(diolefin)(LL)] or [Rh(dppe)2]SnClX2 (X = Cl or Br) are described. The temperature dependence of the 31P NMR spectra and the 1J(Rh, P) and 2j(Sn, P) values are discussed. © 1980.