Hydroformylation of 1-hexene under mild conditions catalyzed by various μ-pyrazolato dirhodium(I) complexes

  1. Kalck, P.
  2. Thorez, Alain.
  3. Pinillos, M.T.
  4. Oro, L.A.
  1. 1 Laboratoire de Chimie Minérale et de Cristallochimie, Ecole Nationale Supérieure de Chimie, 118 route de Narbonne, 31077 Toulouse CédexFrance
  2. 2 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Journal of Molecular Catalysis

ISSN: 0304-5102

Año de publicación: 1985

Volumen: 31

Número: 3

Páginas: 311-315

Tipo: Artículo

SCOPUS: 2-s2.0-0022112328 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Molecular Catalysis

Resumen

The selective hydroformylation reaction of 1-hexene into the corresponding aldehydes has been achieved under very mild conditions of pressure and temperature by various catalyst precursors of the type [Rh2(μ-pyrazolato) 2(CO)2L2] where L = P(OR)3 or PPh3. The electronic effects of the ligands, which play an essential role in the reaction rates, are discussed. © 1985.