Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(: P -SPhCO2Me)]n

  1. Lavenn, C. 2
  2. Guillou, N. 3
  3. Monge, M. 1
  4. Podbevšek, D. 2
  5. Ledoux, G. 2
  6. Fateeva, A. 2
  7. Demessence, A. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Claude Bernard University Lyon 1
    info

    Claude Bernard University Lyon 1

    Villeurbanne, Francia

    ROR https://ror.org/029brtt94

  3. 3 Versailles Saint-Quentin-en-Yvelines University
    info

    Versailles Saint-Quentin-en-Yvelines University

    Versalles, Francia

    ROR https://ror.org/03mkjjy25

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Journal:
Chemical Communications

ISSN: 1359-7345

Year of publication: 2016

Volume: 52

Issue: 58

Pages: 9063-9066

Type: Article

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DOI: 10.1039/C5CC10448C SCOPUS: 2-s2.0-84978922983 WoS: WOS:000379431000020 GOOGLE SCHOLAR

More publications in: Chemical Communications

Abstract

The first structure elucidation of a lamellar gold thiolate coordination polymer is described. [Au(p-SPhCO2Me)]n is obtained from the simultaneous esterification of mercaptobenzoic acid and reduction of the Au(iii) precursor. Despite the presence of aurophilic interactions, the intense phosphorescence (QY ∼ 70%) originates from intra-ligand and metal-to-ligand transitions. © The Royal Society of Chemistry 2016.