Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol.

  1. López-De-Luzuriaga, J.M. 1
  2. Sladek, A. 1
  3. Schmidbaur, H. 1
  1. 1 Technical University Munich
    info

    Technical University Munich

    Múnich, Alemania

    ROR https://ror.org/02kkvpp62

Revista:
Journal of the Chemical Society-Dalton Transactions

ISSN: 0300-9246

Año de publicación: 1996

Volumen: 24

Páginas: 4511-4512

Tipo: Artículo

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Otras publicaciones en: Journal of the Chemical Society-Dalton Transactions

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Resumen

Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh3)3]BF4 afforded a dinuclear complex [Au2(PPh3)3{SCH2CH(OH)CH 2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.