Ylide-Gold(I) Complexes of the types [Au(ylide)L],[Au(ylide)(C=CR)] and [Au(ylide)Co(CO)4 ].

  1. Aguirre, Carlos J . 1
  2. Gimeno, M.C. 1
  3. Laguna, A. 1
  4. Laguna, M. 1
  5. López de Luzuriaga, J.M. 12
  6. Puente, F. 1
  1. 1 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Inorganica Chimica Acta

ISSN: 0020-1693

Año de publicación: 1993

Volumen: 208

Número: 1

Páginas: 31-36

Tipo: Artículo

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Otras publicaciones en: Inorganica Chimica Acta

Resumen

Displacement of tetrahydrothiophene (tht) from [Au(ylide)(tht)]ClO4 (ylide CH2PPh3, CH2PPh2Me, CH2PPhMe2, CHPhPPh3, CHMePPh3 or CH2AsPh3) by other neutral or anionic ligands leads to the mono- and dinuclear cationic complexes [Au(ylide)L]ClO4 (L SbPh3 or phen) or [{Au(ylide)}2(L-L)]ClO4 (L-L dppm or dpam), complexes with tetracarbonylcobaltate as ligand [Au(ylide){Co(CO)4}] or acetylide complexes [Au(ylide)(CCR)] (R Ph or 1Bu). The structure of [Au(CH2PPhMe2)(phen)]ClO4 was established by single-crystal X-ray diffraction studies. © 1993.