Size- and Shape-Control of Crystalline Zinc Oxyde Nanoparticles: A New Organometallic Synhtetic Method

  1. Kahn, M.L. 2
  2. Monge, M. 2
  3. Collière, V. 2
  4. Senocq, F. 1
  5. Maisonnat, A. 2
  6. Chaudret, B. 2
  1. 1 Inter university Material Research and Engineering Centre
    info

    Inter university Material Research and Engineering Centre

    Tolosa, Francia

    ROR https://ror.org/03xhggy77

  2. 2 Laboratoire de Chimie de Coordination
    info

    Laboratoire de Chimie de Coordination

    Tolosa, Francia

    ROR https://ror.org/01rtzw447

Zeitschrift:
Advanced Functional Materials

ISSN: 1616-301X

Datum der Publikation: 2005

Ausgabe: 15

Nummer: 3

Seiten: 458-468

Art: Artikel

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DOI: 10.1002/ADFM.200400113 SCOPUS: 2-s2.0-15944418223 GOOGLE SCHOLAR

Andere Publikationen in: Advanced Functional Materials

Institutionelles Repository: lock_openOpen Access Editor

Zusammenfassung

A novel organometallic synthetic method has been developed for the preparation of crystalline ZnO nanoparticles of controlled size and shape. Isotropic nanoparticles with a mean size between 3 and 6 nm and nanorods with a mean diameter of 3-4 nm and length up to 120 nm have been obtained in this way. This synthetic method takes advantage of the exothermic reaction of the precursor Zn(c-C6H11)2 (1) toward moisture and air and involves the presence of long-alkyl-chain amines as stabilizing ligands. The influence of the different experimental parameters (concentration, solvent, nature of the ligand, time, and temperature) on the size and shape of the ZnO nanoparticles has been studied, together with the mechanism of their formation, by NMR spectroscopy, transmission electron microscopy, and X-ray diffraction techniques. The nanoparticles prepared in this way can be dissolved in most of the common organic solvents, forming colloidal solutions. The surface state of the nanoparticles as well as the possibility of forming luminescent solutions from which regular monolayers can be deposited are also reported. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.