(Trimethylphosphine)(tryphenylsilyl)gold(I) and related compounds.

  1. Oroz, M.M. 2
  2. Schier, A. 1
  3. Schmidbaur, H. 1
  1. 1 Technical University Munich
    info

    Technical University Munich

    Múnich, Alemania

    ROR https://ror.org/02kkvpp62

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Revista:
Zeitschrift für Naturforschung. B, A Journal of Chemical Sciences

ISSN: 0932-0776

Año de publicación: 1999

Volumen: 54

Número: 1

Páginas: 26-29

Tipo: Artículo

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SCOPUS: 2-s2.0-0040121910 WoS: WOS:000078511700006 GOOGLE SCHOLAR

Otras publicaciones en: Zeitschrift für Naturforschung. B, A Journal of Chemical Sciences

Resumen

Mononuclear coordination compounds of the type (R3P)AuSiR'3 with R = R' = Ph and R = Me, R' = Ph have been obtained from reactions of the corresponding halide complexes (R3P)AuCl with the silyllithium reagent LiSiPh3. The fully phenylated species undergoes ligand redistribution in solution to give homoleptic ionic species. (Me3P)AuSiPh3 is less susceptible to this process and crystallizes from solutions as the heteroleptic complex. The crystal structure of this compound has been determined by X-ray diffraction. In the crystal lattice the molecules are not associated.