Perfluoroarylgold Complexes

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. Olmos, M.E. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Journal:
Coordination Chemistry Reviews

ISSN: 0010-8545

Year of publication: 2008

Volume: 252

Issue: 15-17

Pages: 1630-1667

Type: Article

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DOI: 10.1016/J.CCR.2007.11.028 SCOPUS: 2-s2.0-44949098583 WoS: WOS:000257622600009 GOOGLE SCHOLAR

More publications in: Coordination Chemistry Reviews

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Abstract

The number of arylgold complexes has increased considerably, thanks to the use of perfluoroaryl groups, which confer the compounds a higher thermodynamic and kinetic stability. The present review covers the evolution of the knowledge on perfluoroarylgold chemistry since 1994. It focuses not only on the synthesis and structures, but also on the possible applications, such as those derived from the optical properties. Particular attention has been devoted to homo- or hetero-nuclear compounds displaying intra- or intermolecular metal-metal interactions. The complexes cited in this review are organized attending to the non-aryl ligand/s bonded to gold, going from the simplest ones (halides) to the non-classic ferrocene derivatives or metalloligands. © 2007 Elsevier B.V. All rights reserved.