Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand

  1. Fuentes, M.A. 2
  2. Rodríguez-Castillo, M. 1
  3. Monge, M. 1
  4. Olmos, M.E. 1
  5. López-De-Luzuriaga, J.M. 1
  6. Caballero, A. 2
  7. Pérez, P.J. 2
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Universidad de Huelva
    info

    Universidad de Huelva

    Huelva, España

    ROR https://ror.org/03a1kt624

Revista:
Inorganica Chimica Acta

ISSN: 0020-1693

Año de publicación: 2011

Volumen: 369

Número: 1

Páginas: 146-149

Tipo: Artículo

DOI: 10.1016/J.ICA.2011.01.012 SCOPUS: 2-s2.0-79953847671 WoS: WOS:000289279200021 GOOGLE SCHOLAR

Otras publicaciones en: Inorganica Chimica Acta

Resumen

The complexes [Au 2M 2(C 6F 5) 4(NCMe) 2] n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C 6F 5) 2 unit acting as a spectator ligand in both cases. © 2011 Elsevier B.V. All rights reserved.