Gold-thallium supramolecular arrays with 4,4'-bipyridine. Solvent induction of luminescent networks.

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. López-de-Luzuriaga, J.M. 1
  4. Olmos, M.E. 1
  5. Pérez, J. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Journal:
Dalton Transactions

ISSN: 1477-9226

Year of publication: 2004

Volume: 12

Pages: 1801-1806

Type: Article

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DOI: 10.1039/B404703F SCOPUS: 2-s2.0-12444337944 WoS: WOS:000221908400006 GOOGLE SCHOLAR

More publications in: Dalton Transactions

Abstract

The reaction of [AuTl(C6Cl5)2] n with bipy at different molar ratios, solvents or crystallisation conditions affords a series of two- and three-dimensional luminescent complexes, [AuTl(C6Cl5)2(bipy)0.5] n, [AuTl(C6Cl5)2(bipy)] n, {[Tl(bipy)] [Tl(bipy)0.5 (THF)][Au(C6Cl 5)2]2}n, {[Tl(bipy)][Tl(bipy) 0.5(THF)][Au(C6Cl5)2] 2·THF}n and {[AuTl(C6Cl 5)2(bipy)].0.5toluene}n (bipy = 4,4′-bipyridine; THF = tetrahydrofuran) all of them containing polymeric chains formed via unsupported Au...Tl interactions and bridging bipyridine ligands. © The Royal Society of Chemistry 2004.