Phosphinethiolate tin(IV)-11 group-metal derivatives. X-ray structure of [Au2Sn(tBu)2(C6F5)2(SC6H4PPh2)2]

  1. Fernández, E.J. 1
  2. Hursthouse, M.B. 2
  3. Laguna, M. 3
  4. Terroba, R. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 University of Wales
    info

    University of Wales

    Cardiff, Reino Unido

    ROR https://ror.org/01se4f844

  3. 3 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

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Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Año de publicación: 1999

Volumen: 574

Número: 2

Páginas: 207-212

Tipo: Artículo

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SCOPUS: 2-s2.0-0033580184 WoS: WOS:000079056500001 GOOGLE SCHOLAR

Otras publicaciones en: Journal of Organometallic Chemistry

Resumen

[SnR2Cl2] reacts with (SC6H4PPh2)- giving [SnR2(SC6H4PPh2)2] (R=Me, tBu, Ph) (1a-c). These compounds can displace tetrahydrothiophene from [Au(C6F5)(tht)] or [Au(tht)2]ClO4 or reacts with AgClO4. Complexes [SnR2{(SC6H4PPh2)Au(C6F5)}2] (2a-c) and [SnR2(SC6H4PPh2)2M]ClO4 (M=Au 3a-c; M=Ag 4a-c) are obtained. The crystal structure of [Sn(tBu)2{(SC6H4PPh2)Au(C6F5)}2] (2b) has been established by X-ray diffraction.