[Tl(OPPh3)2][Au(C6F5)2]: the first extended unsupported gold-thallium linear chain
- Crespo, O. 2
- Fernández, E.J. 1
- Jones, P.G. 3
- Laguna, A. 2
- López-de-Luzuriaga, J.M. 1
- Mendía, A. 1
- Monge, M. 1
- Olmos, E. 1
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1
Universidad de La Rioja
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2
Instituto de Nanociencia y Materiales de Aragón
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3
Braunschweig University of Technology
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ISSN: 1359-7345
Any de publicació: 1998
Volum: 20
Número: 20
Pàgines: 2233-2234
Tipus: Article
beta Ver similares en nube de resultadosAltres publicacions en: Chemical Communications
Resum
Li[Au(C6F5)2] reacts with TlNO3 in the presence of OPPh3 affording a complex of stoichiometry [AuTl(C6F5)2-(OPPh3) 2]n, which presents different luminescence properties depending on the conditions and whose crystal structure reveals the existence of unsupported Au-Tl bonds forming a polymeric linear chain.