Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)2{(SPPh2)2C(AuAsPh3)2}]ClO4.

  1. Alvarez, B. 1
  2. Fernández, E.J. 1
  3. Gimeno, M.C. 2
  4. Jones, P.G. 3
  5. Laguna, A. 2
  6. López-de-Luzuriaga, J.M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Revista:
Polyhedron

ISSN: 0277-5387

Ano de publicación: 1998

Volume: 17

Número: 11/12/2010

Páxinas: 2029-2035

Tipo: Artigo

SCOPUS: 2-s2.0-0001610689 WoS: WOS:000073949000029 GOOGLE SCHOLAR

Outras publicacións en: Polyhedron

Resumo

The reaction between the chalcogenide derivatives [Au(C6F5)3(PPh2CH 2PPh2E)] (E = S, O) and [Au(acac)PPh3] or [Au(TfO)PPh3] leads to the dinuclear compounds [Au(C6F5)3{PPh2CH(AuPPh 3)PPh2E}] (E = S, O) or [Au(C6F5)3{PPh2CH 2PPh2(SAuPPh3)}], respectively. When the phosphine disulphide complex [Au(C6F5)3(SPPh2CH 2PPh2S)] is employed, the reaction with [Au(acac)PPh3] promotes the double substitution of the methylenic protons. The reaction of [Au(acac)L] (L = PPh3, AsPh3) with the six-membered auracycle [Au(C6F5)2{(SPPh2)2CH 2}]ClO4 leads to the double substitution of both methylenic protons by [AuL]+ fragments, keeping the auracycle intact. The crystal structure of one such product, [Au(C6F5)2{(SPPh2) 2C(AuAsPh3)2}]ClO4 has been established by X-ray diffraction studies. Starting from the methanide derivative [Au(C6F5)2(SPPh2CHPPh 2S)], the reaction with [Au(acac)PPh3] leads to the synthesis of the four-membered ring methanide [Au(C6F5)2{SPPh2C(AuPPh 3)PPh2S}] © 1998 Elsevier Science Ltd. All rights reserved.