Synthesis of hetheropolynuclear complexes using new tin(IV) dimers. X-ray structure of [AuSnCl(tBu)2(SC6H4)(PPh3)]

  1. Fernández, E.J. 1
  2. Hursthouse, M.B. 2
  3. Laguna, M. 3
  4. Terroba, R. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 University of Wales
    info

    University of Wales

    Cardiff, Reino Unido

    ROR https://ror.org/01se4f844

  3. 3 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

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Revista:
Organometallics

ISSN: 0276-7333

Año de publicación: 1997

Volumen: 16

Número: 26

Páginas: 5637-5640

Tipo: Artículo

DOI: 10.1021/OM970326P SCOPUS: 2-s2.0-0040486638 WoS: WOS:000071423300015 GOOGLE SCHOLAR

Otras publicaciones en: Organometallics

Repositorio institucional: lock_openAcceso abierto Editor

Resumen

Li2(SC6H4) reacts with [SnR2Cl2] affording the dinuclear derivatives [{SnR2(SC6H4)}2] (R = Me, tBu, Ph) (1a-c). The reaction of these dimer derivatives with various [AuClL] breaks the tin-sulfur bonds, affording the heterobimetallic complexes [AuSnClR2(SC6H4)L] (L = PPh3, AsPh3, CH2PPh3) (2-4). The synthesis of [Au{SnClMe2(SC6H4)}2] (5) is carried out in a similar way. The lithiated product Li2(SC6H4) can react with [AuCl(PPh3)], giving [Au2(SC6H4)(PPh3)2] (6). The molecular structure of the complex [AuSnCl(tBu)2(SC6H4)(PPh 3)] (2b) has been established by X-ray diffraction and shows a tetrahedral tin center and a linear gold(I) atom bridged by the "C-S" bidentate ligand.