Gold(I) complexes with biologically active thiolate ligands

  1. Concepción Gimeno, M. 2
  2. Jambrina, E. 1
  3. Fernández, E.J. 1
  4. Laguna, A. 2
  5. Laguna, M. 2
  6. Jones, P.G. 4
  7. Merchán, F.L. 3
  8. Terroba, R. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  4. 4 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Revista:
Inorganica Chimica Acta

ISSN: 0020-1693

Any de publicació: 1997

Volum: 258

Número: 1

Pàgines: 71-75

Tipus: Article

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SCOPUS: 2-s2.0-0041194694 WoS: WOS:A1997XD85400009 GOOGLE SCHOLAR

Altres publicacions en: Inorganica Chimica Acta

Repositori institucional: lock_openAccés obert Editor

Resum

The reaction of ethanolic solutions of Na(SR) (SR = 4-oxo-2-thioxopyrimidines) with [AuClL] (L = PPh3, PPh2Me and AsPh3) gives [Au(SR)L]; when PPN[AuCl2] or NBu4[AuBr(C6F5)] are used instead, PPN[Au(SR)2] and NBu4[Au(C6F5) (SR)] are obtained. The structure of [Au(SR1) (PPh3)] has been established by X-ray diffraction, and shows a linear coordination at gold involving the phosphine phosphorus and the exocyclic sulfur atom of the organic ligand.