Synthesis and structure of [Tl(C6F5)2Cl{Au(C6F5)3(PPh2CH2PPh2(O))}2].

  1. Alvarez, B. 1
  2. Fernández, E.J. 1
  3. Gimeno, M.C. 1
  4. Jones, P.G. 3
  5. Laguna, A. 2
  6. Laguna, M. 2
  7. López-de-Luzuriaga, J.M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Journal:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Year of publication: 1996

Volume: 525

Issue: 1-2

Pages: 109-113

Type: Article

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SCOPUS: 2-s2.0-0030588882 WoS: WOS:A1996WA21200014 GOOGLE SCHOLAR

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Abstract

Two trinuclear gold-thallium-gold complexes, [T1(C6F5)2X{Au(C6F5)3(PPH2CH2PPh2CH2PPh2(O))}2} (X = C6F5, C1), have been synthesised by reaction of [Au(C6F5)3(PPh2(O))] with [T1(C6F5)2C1] or [T1(C6F5)3(diox)], in which the phosphine oxide moiety coordinates to thallium; the crystal structure of the former product has been established by X-ray diffraction.