Dihalo(tetraphenyldithioimidodiphosphinato)gold(III) complexes. Crystal and molecular structure of [AuCl2(SPPh2NPPh2S)]

  1. Laguna, A. 1
  2. Laguna, M. 1
  3. Fraile, M.N. 1
  4. Fernandez, E. 1
  5. Jones, P.G. 2
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 University of Göttingen
    info

    University of Göttingen

    Gotinga, Alemania

    ROR https://ror.org/01y9bpm73

Revue:
Inorganica Chimica Acta

ISSN: 0020-1693

Année de publication: 1988

Volumen: 150

Número: 2

Pages: 233-236

Type: Article

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SCOPUS: 2-s2.0-0039448130 WoS: WOS:A1988Q669500022 GOOGLE SCHOLAR

D'autres publications dans: Inorganica Chimica Acta

Résumé

The reaction of SPPh2NPPh2S with AuCl3(tht) gives AuCl2(SPPh2NPPh2S), containing the deprotonated ligand. Oxidations with halogens (X = Cl, Br or I) of [Au(SPPh2NPPh2S)]2 leads to AuX2(SPPh2NPPh2S). The structure of the dichloro complex has been determined by X-ray crystallography. © 1988 Elsevier Sequoia.