The spontaneous formation and plasmonic properties of ultrathin gold-silver nanorods and nanowires stabilized in oleic acid
- Crespo, J. 1
- López-De-Luzuriaga, J.M. 1
- Monge, M. 1
- Elena Olmos, M. 1
- Rodríguez-Castillo, M. 4
- Cormary, B. 4
- Soulantica, K. 4
- Sestu, Matteo . 2
- Falqui, A. 3
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1
Universidad de La Rioja
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2
University of Cagliari
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3
King Abdullah University of Science and Technology
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King Abdullah University of Science and Technology
Jeddah, Arabia Saudí
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4
Université de Toulouse
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Université de Toulouse
Tolosa, Francia
ISSN: 1359-7345
Year of publication: 2015
Volume: 51
Issue: 93
Pages: 16691-16694
Type: Article
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Abstract
Ultrathin Au-Ag alloy nanorods and nanowires of different lengths and ca. 1.9 nm diameter are prepared through a low-temperature decomposition of the precursor [Au2Ag2(C6F5)4(OEt2)2]n in oleic acid. This nanostructure formation has been studied through TEM, HRTEM, EDS, HS-SPME-GC-MS and 19F NMR spectroscopy. The UNRs and UNWs display a length-dependent broad band in the mid-IR region that is related to the longitudinal mode of the surface plasmon resonance of the ultrathin nanostructures. © The Royal Society of Chemistry 2015.