Photophysical Studies and Excited-State Structure of a Blue Phosphorescent Gold-Thallium Complex

  1. Fernández, E.J. 2
  2. Laguna, A. 1
  3. López-de-Luzuriaga, J.M. 2
  4. Monge, M. 2
  5. Montiel, M. 2
  6. Olmos, M.E. 2
  1. 1 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  2. 2 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Inorganic Chemistry

ISSN: 0020-1669

Year of publication: 2007

Volume: 46

Issue: 8

Pages: 2953-2955

Type: Article

DOI: 10.1021/IC062127G PMID: 17373786 SCOPUS: 2-s2.0-34247875860 WoS: WOS:000245510200004 GOOGLE SCHOLAR

More publications in: Inorganic Chemistry

Metrics

Cited by

  • Scopus Cited by: 38 (12-01-2023)
  • Web of Science Cited by: 34 (06-02-2023)

JCR (Journal Impact Factor)

  • Year 2007
  • Journal Impact Factor: 4.123
  • Journal Impact Factor without self cites: 3.36
  • Article influence score: 1.061
  • Best Quartile: Q1
  • Area: CHEMISTRY, INORGANIC & NUCLEAR Quartile: Q1 Rank in area: 4/43 (Ranking edition: SCIE)

SCImago Journal Rank

  • Year 2007
  • SJR Journal Impact: 2.165
  • Best Quartile: Q1
  • Area: Inorganic Chemistry Quartile: Q1 Rank in area: 6/70
  • Area: Chemistry (miscellaneous) Quartile: Q1 Rank in area: 26/403
  • Area: Physical and Theoretical Chemistry Quartile: Q1 Rank in area: 16/156

Abstract

The dinuclear complex {[TI(η6-toluene)][Au(C 6Cl5)2]} (1) displays very intense blue phosphorescence and a rigidochromic behavior in the solid state. The photophysical measurements in a glassy solution display an oligomerization process via metal-metal interactions. Density functional theory calculations show a distortion of the aurate-thallium T shape in the lowest triplet excited state, leading to a triplet metal-to-metal charge-transfer state. © 2007 American Chemical Society.