Combining Aurophilic Interactions and Halogen Bonding To Control the Luminescence from Bimetallic Gold-Silver Clusters

  1. Laguna, A. 2
  2. Lasanta, T. 1
  3. López-de-Luzuriaga, J.M. 1
  4. Monge, M. 1
  5. Naumov, P. 3
  6. Olmos, M.E. 3
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Osaka University
    info

    Osaka University

    Osaka, Japón

    ROR https://ror.org/035t8zc32

Revista:
Journal of the American Chemical Society

ISSN: 0002-7863

Año de publicación: 2010

Volumen: 132

Número: 2

Páginas: 456-457

Tipo: Artículo

DOI: 10.1021/JA909241M SCOPUS: 2-s2.0-74949130957 WoS: WOS:000275084600014 GOOGLE SCHOLAR

Otras publicaciones en: Journal of the American Chemical Society

Resumen

(Figure Presented) The luminescence in a series of new bimetallic gold-silver vapochromic structures can be efficiently switched among different colors simply by exposure to solvent vapors. The emission color in these systems is controlled by both aurophilic interactions and halogen bonding, which affect the emission energy through different orbitals. Copyright © 2010 American Chemical Society.