Synthesis of Enantiopure Quaternary Prolines by a Metathesis Process of 2,5-Ethenoproline Derivatives

  1. Carreras, J. 1
  2. Avenoza, A. 1
  3. Busto, J.H. 1
  4. Peregrina, J.M. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

Journal:
Synthesis (Stuttgart)

ISSN: 0039-7881

Year of publication: 2010

Volume: 19

Pages: 3353-3357

Type: Article

DOI: 10.1055/S-0030-1257907 SCOPUS: 2-s2.0-77957123339 WoS: WOS:000282106600020 GOOGLE SCHOLAR

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Abstract

A novel azabicyclic amino acid was synthesized in both enantiopure forms. The ring-opening metathesis of methyl N-(tert-butoxycarbonyl)-7-azabicyclo[2.2. 1]hept-2-ene-1-carboxylates was used as a method for accessing a new family of enantiopure proline analogues. © Georg Thieme Verlag Stuttgart New York.