Alkylidene Transfer from Monochloroalkylmercury(II) Compounds to Aromatic Amines; Selective C-Alkylation
- Barluenga, J. 1
- Campos, P.J. 1
- Roy, M.A. 1
- Asensio, G. 1
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1
Universidad de Oviedo
info
ISSN: 0300-922X
Année de publication: 1980
Pages: 1420-1426
Type: Article
D'autres publications dans: Journal of the Chemical Society-Perkin Transactions n 1
Résumé
α,α-Diarylalkane derivatives have been synthesized from monochloroalkylmercury(II) compounds in a non-carbenoid alkylidene transfer reaction which takes place selectively on the aromatic ring. A mechanism is suggested for this process. Intermediate products are prepared by alternative routes to ascertain their participation in the course of the reaction. As a consequence, two different aryl groups can be successively incorporated into the alkane molecule.